Role of anion•••π interactions in photochemical [2+2] cycloaddition reaction
Ashutosh Sharan Singh ()Inspired by biological processes, anion•••π interactions1 have been explored in multidisciplinary areas of research such as recognition and sensing2, catalysis3, etc. Because of the weak nature of anion•••π interactions, such interaction is still a challenging task to explore in an artificial system, especially in a polar solvent(s). In this presentation, we will discuss the role of the anion (as template) in photochemical [2+2] cycloaddition reaction through anion•••π interactions to form a four-membered cyclic ring.
The hydrogen atom of such a four-membered ring is very sensitive to pH and temperature. The main problem is the removal of the template after the photochemical [2+2] cycloaddition reaction. Anion (as a template) can be removed easily. The complete process and role of anion•••π interactions will be discussed in the present conference.
Keywords: Anion•••π interactions, photochemical [2+2] cycloaddition reaction, hydrogen-bond.
-
1.
Plais, R.; Clavier, G.; Salpin, J. -Y.; Gaucher, A.; Prim, D. Eur. J. Org. Chem. 2023, 23(9) (DOI: 10.1002/ejoc.202201281).
-
2.
Chen-Yen Hung, Ashutosh S. Singh, Chih-Wei Chen, Yuh-Sheng Wen, Shih-Sheng Sun* Chem. Commun. 2009, 45, 1511-1513 (DOI: 10.1039/b820234f).
-
3.
Zhao, Y.; Cotelle, Y..; Liu, L.; Ló pez-Andarias, J.; Bornhof, A. -B.; Akamatsu, M.; Sakai, N.; Matile, S. Acc. Chem. Res. 2018, 51(9), 2255–2263.
| Section | Poster Presentation |
|---|
Most read articles by the same author(s)
- Ashutosh Sharan Singh, Sarvjeet Kaur, Effect of substituents on mutual induced-fit controlled hydrogen-bonded capsule formation , RSYN Proceedings: Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)
- Ashutosh Sharan Singh, Sonika, Selective sensing of Hg2+ ion by N-bridged ligand , RSYN Proceedings: Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)
- Ashutosh Sharan Singh, Mehak, Simran Singh, Sonika, Structural tunning of hydrogen-bonded motifs in response of an external stimuli to form 2D-sheet and 3D-HOFs from 1D-chain in the solid-state , RSYN Proceedings: Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)
- Ashutosh Sharan Singh, Simiran, Sonika Garg, Importance of stimuli responsive confined space , RSYN Proceedings: Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)
Similar Articles
- Swapnil Chaturvedi, Advancing Eco-Efficient Processes Across Pharmaceutical, Fragrance, and Agrochemical Sectors , RSYN Proceedings: Vol. 2 No. 4 (2025): Integrating Green Chemistry into Academia and Industry for Sustainable Development
- Amalendu Pal, Micellization behavior of anionic ionic liquid 1-butyl-3-methyl imidazolium dodecylbenzenesulphonate in the presence ofcationic polyelectrolyte PDADMAC and non-ionic polyelectrolyte PVP: Insights into competing mechanism , RSYN Proceedings: Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)
- Aditi Bansal, Dr. Swapnil Chaturvedi, Green Nanobiotechnology: Sustainable Advancements in Healthcare, Agriculture, and Environmental Remediation , RSYN Proceedings: Vol. 2 No. 4 (2025): Integrating Green Chemistry into Academia and Industry for Sustainable Development
- Sania, From Silicon to Sustainability, 2D FETs as Building block for Green Electronics , RSYN Proceedings: Vol. 2 No. 4 (2025): Integrating Green Chemistry into Academia and Industry for Sustainable Development
- Ajay Kumar Mishra, Nanotechnology for environmental sustainability , RSYN Proceedings: Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)
- PRATEEK, NAMAN BERI, Prof. Ravneet Kaur, Prof. Anju Agrawal, Dr. Monika Bhattacharya , An Integrated Data Science Pipeline for Biological and Environmental Insights: AI-Driven Trend Detection Aligned with Ecological and Sustainable Development Goals , RSYN Proceedings: Vol. 2 No. 4 (2025): Integrating Green Chemistry into Academia and Industry for Sustainable Development
- Ashutosh Sharan Singh, Sonika, Selective sensing of Hg2+ ion by N-bridged ligand , RSYN Proceedings: Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)
- Mr. Deepak Malik, Dr. Renu Sharma, Dr. Tejbir Singh, Mass Attenuation Coefficient of Some Bismuth-Based Alloys for Gamma-Ray Shielding: Theoretical and Experimental Approach , RSYN Proceedings: Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)
You may also start an advanced similarity search for this article.