Importance of stimuli responsive confined space
Ashutosh Sharan Singh, Simiran, Sonika Garg ()Molecular behaviour changes drastically in a confined space in comparison to their corresponding bulk phase. A confined space also available to trap/encapsulate a guest molecule. In an artificial system, such confined space also termed as cavity formed through judicial choice of either only organic ligand (termed as capsule) or with suitable metal-ion (termed as metallacapsule). Molecular capsule formed by non-covalent interactions gets benefit of reversible assembly in response to an external stimulus through dynamic self-assembly.
In this presentation we will discuss about encapsulation of notorious and toxic nitrate anion and their role in the formation and isolation of single isomer, formed by photochemical [2+2] cycloaddition reaction with mechanistic point of view.
| Section | Poster Presentation |
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| Pages | PP05 |
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