Structural tunning of hydrogen-bonded motifs in response of an external stimuli to form 2D-sheet and 3D-HOFs from 1D-chain in the solid-state

Ashutosh Sharan Singh; Mehak; Simran Singh; Sonika; Ashutosh Sharan Singh; Mehak; Simran Singh; Sonika

doi:10.70130/

Structural tunning of hydrogen-bonded motifs in response of an external stimuli to form 2D-sheet and 3D-HOFs from 1D-chain in the solid-state

Ashutosh Sharan Singh, Mehak, Simran Singh, Sonika ()

Submitted2025-03-31Published2025-03-31Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)

Abstract

Molecules in their solid state are tightly packed through various modes of interaction, and their crystal forms are highly fragile in response to external stimuli/disturbance, especially if they are connected through weak hydrogen bonds. In this presentation, we are going to highlight the transformation of anion-templated hydrogen-bonded 1D motifs to 2D-sheet1 and 3D-HOFs², respectively, in response to an external stimulus such as light and heat. During this transformation, molecule covers a remarkable distance in their corresponding crystal forms, stabilized by anion•••π interactions. In this presentation, we will discuss the complete process with mechanistic studies.

Keywords:hydrogen-bonded motifs ,3D-HOFs

References

1.
1. Ashutosh S. Singh, Ranjay K. Tiwari, Mandy M. Lee, Jogendra N. Behera,
Google Scholar PubMed
2.
Shih-Sheng Sun, V. Chandrasekhar Chem. -Eur. J. 2017, 23, 762 – 766.
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2. Ashutosh S. Singh, Ranjay K. Tiwari, Jogendra N. Behera, Shih-Sheng Sun, V. Chandrasekhar CrystEngComm, 2018, 20, 2346 – 2350.
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Published

March 31, 2025

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Vol. 2 No. 1 (2025): 3rd International Conference on Recent Advances in Applied Sciences (ICRAAS-2025)

How to Cite

Singh, A. S., Mehak, Singh, S., & Sonika. (2025). Structural tunning of hydrogen-bonded motifs in response of an external stimuli to form 2D-sheet and 3D-HOFs from 1D-chain in the solid-state. RSYN Proceedings, 2(1). https://doi.org/10.70130/

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Section	Poster Presentation

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Structural tunning of hydrogen-bonded motifs in response of an external stimuli to form 2D-sheet and 3D-HOFs from 1D-chain in the solid-state

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